Product ID:POLYROOF, 361-589L-996
MSDS Date:06/01/1989
FSC:8030
NIIN:00N019811
MSDS Number: BLLZW

TREMCO

10701 SHAKER BLVD
CLEVELAND, OH 44104
US

Emergency Phone: 216-765-6727; 800-424-9300

Info Phone: 216-292-5000

Preparer: F L MILLER

Cage: TRMC0

TREMCO INC

CLEVELAND, OH 44128 US

Telephone: 216-752-4400

Cage: 94529

ASPHALT (PETROLEUM)

CAS: 8052-42-4

RTECS: CI9900000

Fraction By Weight: 35%

ACGIH TLV: 5 MG/M3; (FUME);9192

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 24%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CRYSTALLINE SILICA; (SILICA (AMORPHOUS))

CAS: 7631-86-9

Fraction By Weight: 10%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 7%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED HEAVY

CAS: 64742-52-5

RTECS: PY8035000

Fraction By Weight: 5%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

COAL TAR PITCH VOLATILES (BENZENE SOLUBLE FRACTION),

CAS: 65996-93-2

RTECS: GF8655000

Fraction By Weight: 5%

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3, A1; 9192

REACH OF CHILDREN.

RTECS: 9999999ZZ

CNTCT W/SKIN. GLOVES MUST BE CHECKED BEFORE

RTECS: 9999999ZZ

PROPER FUNCTIONING.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:CAN CAUSE IRRIT. SKIN:CAN
CAUSE IRRIT/DERM/POSS PHOTOSENSIT. INHAL:CAN CAUSE HDCH/DIZZ/IRRIT
TO RESP SYS. INGEST:CAN CAUSE GI IRRIT. CHRONIC:RPTS HAVE ASSOC
RPTD/PRLNG OCCUP OVEREXP TO SOLVS W/PERMANENT BRAIN & NERV SYS
DMG. INTENT MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE
HARMFUL/FATAL. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:COAL TAR PITCH VOLATILES:GROUP 1(IARC).
CAS NO.64742-52-5 IS LISTED AS AN IARC GROUP 1 CARCINOGEN.
Effects of Overexposure:HLTH HAZ:ASPHALT CONTAINS SM AMTS OF
POLYNUCLEAR AROMATIC CMPDS WHICH HAVE BEEN SHOWN TO CAUSE CANCER &
RESP DMG IN LAB ANIMALS. THERE ARE NO AVAIL STUDIES THAT INDICATE
ASPHALT CAUSES CANCER/RESP DMG IN HUMANS. COAL TAR & PITCH CAN
CAUSE CANCER OF LUNG/SKIN/ BLADDER/GI TRACT. OVEREXP TO XYLENE CAN
ADVERSLY (SUPP DATA)
Medical Cond Aggravated by Exposure:EXPOSURE TO NAPHTHENIC DISTILLATE
CAN AGGRAVATE EXISTING SKIN & RESPIRATORY DISORDERS.

First Aid:SKIN:WASH AREA OF CNTCT THORO W/HAND CLEANER FOLLOWED BY SOAP
& H2O. IF IRRIT/RASH/OTHER DISORDERS DEVEL, GET MD IMMED.
EYES:FLUSH IMMED W/RUNNING H2O FOR @ LST 15 MIN, LIFTING UPPER &
LOWER LIDS OCCA S. GET MD IMMED. INGEST:GET MD IMMED. INHAL:LEAVE
AREA TO BREATHE FRESH AIR. AVOID FURTHER OVEREXP. IF SYMPTOMS
PERSIST, GET MD IMMED.

Extinguishing Media:CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
CONTAINER (EVEN EMPTY). PRODUCT, RESIDUE, VAPOR MAY IGNITE.

Spill Release Procedures:ABSORB SPILL IN SAND, EARTH OR OTHER SUITABLE
MATERIAL. TRANSFER TO APPROPRIATE CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLSD CNTNR BELOW 80F. KEEP
PROD & VAP AWAY FROM HEAT/SPKS/FLAME. DO NOT STORE IN DIRECT
SUNLIGHT. PVNT INHAL OF VAP/INGEST/CNTCT W/SKIN/EYES.
Other Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. VAP MAY MIGRATE TO
SOURCES OF IGNIT. DO NOT SMOKE/WELD/GENERATE SPKS/USE FLAME NEAR
CNTNR. PERSONAL PROT EQUIP MUST BE WORN DURING MAINT/REPAIR OF
CONTAM MIXER/ REACTO R/OTHER EQUIP. PREC ALSO APPLY TO(SUPDAT

Respiratory Protection:USE APPROPRIATE, PROPERLY FITTED NIOSH/MSHA
APPROVED RESPIRATOR WHEN AIRBORNE CONTAMINANT LEVEL EXCEED TLV.
FOLLOW MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:USE LOCAL EXHAUST WHEN GENERAL VENT IS NOT SUFFICIENT TO
KEEP AIRBORNE CONTAMINANT CONCENTRATION BELOW TLV.
Protective Gloves:IMPERVIOUS RUBBER GLOVES. PVNT (ING 8)
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:TYPICAL FULL COVER CLOTHING.
Work Hygienic Practices:CHANGE SOILED WORKCLOTHES FREQUENTLY. CLEAN
HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:AFFECT CNS/HEART/LIVER/ KIDNEYS/ LUNGS/SPLEEN/ADRENALS.
EMBRYO/FETOTOXICITY OCCURRED IN PREGNANT RATS EXPOSED BY INHAL &
MICE EXPOSED ORALLY(W/MATERAL TOX)TO XYLENE. OVEREXP TO ETHYL B
ENZENE BY INHAL CAUSED LIVER EFTS IN LAB ANIMALS. OTHER
PREC:EMPTIED CNTNRS. FOR INDUS USE ONLY. KEEP OUT OF (INGRED 7)

HCC:V4
Vapor Density:>1
Spec Gravity:0.97
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK PASTE; SOLVENT ODOR.
Percent Volatiles by Volume:35(WT)

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:NOT REGULATED BY RCRA. DISPOSE OF IN COMPLIANCE
WITH FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.